废旧三元正极材料直接再生:修复机制与发展方向

Direct Regeneration of Spent Ternary Lithium-ion Batteries: Repair Mechanism and Development Directions

  • 摘要: 随着储能电站的不断建设和电动汽车市场的持续扩大,未来几年将会产生大量退役的锂离子电池。如果这些电池处理不当,不仅会造成资源的浪费,也会对环境产生不可逆污染。因此,开发高效的退役电池回收技术是推动锂离子电池可持续发展、实现双碳目标的重要途径。目前主要的废旧电池回收方法包括间接回收和直接再生,相比之下,直接再生具有更明显的环境和经济优势。直接再生法通过简单的步骤实现组分的恢复、晶体结构和缺陷的修复,使废旧正极修复为电化学性能优异的全新正极材料,无需分解成单独的元素或破坏原有的晶体结构。本文以废旧锂离子电池中三元正极材料为研究对象,综述了废旧三元正极的失效机制,在失效机制的基础上,分析并总结了不同直接再生法的再生机制和再生效果。接着,从经济效益和环境问题等方面论述了废旧锂离子电池直接再生的广阔发展前景。最后,讨论直接再生法从实验室规模发展到实际生产应用面临的挑战,并提出相应的见解。

     

    Abstract: With the continuous construction of energy storage power stations and the continuous expansion of the electric vehicle market, a large number of retired lithium-ion batteries will be produced in the next few years. If these batteries are not handled properly, it will not only cause a waste of resources, but also cause irreversible pollution to the environment. Therefore, the development of efficient retired battery recycling technology is an important way to promote the sustainable development of lithium-ion batteries and achieve the goal of carbon peaking and carbon neutrality. At present, the main recycling methods of retired batteries include indirect recycling and direct recycling, which has more obvious environmental and economic advantages. The direct regeneration method realizes the recovery of components, the repair of crystal structure and defects through simple steps, so that the spent cathode is transformed into a new cathode with excellent electrochemical performance, which does not need to decompose into separate elements or destroy the original crystal structure. In this paper, the failure mechanism of ternary cathode is summarized. Based on the failure mechanism, the regeneration mechanism and regeneration effect of different direct regeneration methods are analyzed and summarized. Then, the broad development prospect of direct regeneration of waste lithium-ion batteries is discussed from the aspects of economic benefits and environmental problems. Finally, the challenges facing the development of direct regeneration from laboratory scale to practical production applications are discussed, and corresponding insights are provided.

     

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