锂离子电池电热耦合建模综述

Electro-thermal Modeling of Li-ion Batteries: A Review

  • 摘要: 锂离子电池的建模研究由于具有资源消耗少、试验周期短、准确度良好等优点而被广泛应用于电池的性能分析与设计优化中。本文围绕电学与热学层面综述了主流建模方法并阐述了电热模型的耦合机理。电学模型按机理深度可以分为电化学机理模型、等效电路模型与数据驱动模型。其中,电化学机理模型具有较高精度与可解释性,但参数辨识与数值求解复杂度高;等效电路模型结构简单且易于在线实现;数据驱动模型依赖训练数据覆盖度,适用于非线性与复杂工况下的快速映射。热学建模包含产热模型与传热模型,其中产热模型以BERNARDI方程为核心,传热模型可分为集总参数、多维传热与等效热路模型,不同模型在温度分辨率、计算复杂度与工程可部署性上有不同的权衡。在此基础上,本文阐述了电热耦合的实现机理,即电学参数的温度依赖性以及电学参数对产热与温度的影响。最后,针对不同的电学模型与热学模型的组合,给出了具体的耦合实现方法与研究案例,涵盖了从电化学机理-多维传热的高精度模型到等效电路-等效热路的高效率模型,为深入理解锂离子电池的建模策略与模型选择提供了参考。

     

    Abstract: Modeling studies of lithium-ion batteries(LIBs) have been widely employed for performance analysis and design optimization due to their low resource consumption, short experimental cycles, and satisfactory accuracy. Mainstream modeling approaches are reviewed from both electrical and thermal perspectives and the coupling mechanism of electro-thermal models is explained. Electrical models can be categorized into electrochemical mechanistic models, equivalent circuit models and data-driven models according to the depth of physical interpretation. Electrochemical mechanistic models provide high accuracy and strong interpretability, but involve challenging parameter identification and high numerical complexity; equivalent circuit models feature simple structures and are well suited for online implementation; data-driven models depend on the coverage of training data and are effective for fast mapping under nonlinear and complex operating conditions. Thermal modeling consists of heat generation models and heat transfer models. The heat generation models are typically formulated based on the BERNARDI equation, while heat transfer models can be divided into lumped models, multi-dimensional models and equivalent thermal network models, which represent different trade-offs among temperature resolution, computational burden, and engineering deploy ability. On this basis, the electro-thermal coupling mechanism is clarified: the temperature dependence of electrical parameters and the impact of these parameters on heat generation and temperature. Finally, for different combinations of electrical and thermal models, specific coupling implementations and representative cases are presented, covering configurations ranging from high-fidelity electrochemical-multi-dimensional heat transfer models to high-efficiency equivalent-circuit-thermal network models. This review provides references for understanding LIBs modeling strategies and for selecting appropriate models in practice.

     

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