极地低温环境燃料电池冷启动过程模拟仿真研究

Numerical Simulation of Cold Start Process for Fuel Cells in Polar Low-temperature Environments

  • 摘要: 以氢气为燃料的质子交换膜燃料电池(Proton exchange membrane fuel cell, PEMFC)在极地综合能源发电系统中具有巨大的应用潜力,但极地低温(~213.15 K)、低压(0.55~0.95 atm)和低氧含量(20.4%~20.95%)等恶劣环境对PEMFC正常运行提出了巨大挑战。为此,搭建了考虑PEMFC内部热质传输与电化学反应过程的一维瞬态全电池冷启动模型,在模型验证的基础上,对南极科考站区不同环境温度和空气压力条件下PEMFC冷启动过程中的输出电压、内部冰和水的形成分布、电池温度等变化规律进行了深入分析。模拟结果发现,PEMFC在相同电流密度加载下,冷启动温度越低,电压衰减及冰生成速度越快,且在更低温度(<243.15 K)下,电压衰减的主要直接因素将由浓差极化损失转为欧姆极化损失。此外,低温低压下活化极化损失将进一步缩短冷启动过程中PEMFC存活时间。所开发模型和仿真计算结果可为PEMFC在极地科考站区及野外观监测台站的发电系统中的应用研究奠定基础。

     

    Abstract: Proton exchange membrane fuel cell(PEMFC) powered by hydrogen exhibit significant application potential in polar integrated energy power generation systems. However, the harsh environmental conditions prevalent in polar regions, including low temperatures(~213.15 K), reduced atmospheric pressure(0.55-0.95 atm), and low oxygen concentrations(20.4%-20.95%), present substantial challenges to the reliable operation of PEMFCs. To address this, a transient one-dimensional full-cell cold start model considering the internal heat and mass transfer and electrochemical reaction process of PEMFC is proposed. Based on the model verification, an in-depth analysis is conducted on the variation laws of output voltage, the formation and distribution of internal ice and water, and temperature during the cold start process of PEMFC under different environmental temperatures and air pressures in Antarctic research station areas. Simulation results indicate that lower cold-start temperatures accelerate voltage decay and ice formation under a ramp-constant current density profile. At extremely low temperatures(<243.15 K), ohmic polarization loss replaces concentration polarization loss as the primary cause of voltage decline. Furthermore, the activation polarization loss under low temperature and low pressure will further shorten the operational survival time of PEMFC in cold-start processes. The computational model and simulation results provide further research foundations for PEMFCs’ application in polar power systems, supporting their application in research stations and remote monitoring stations.

     

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