锂离子电池枝晶内短路引起的电热效应研究

Study on the Electrothermal Effect Caused by Internal Short Circuit in Lithium-ion Battery Dendrites

  • 摘要: 锂枝晶内短路是造成新能源汽车锂离子电池热失控的主要原因之一,掌握锂离子电池枝晶-温度特性有利于降低锂电池内短路热失控风险。建立锂电池电化学热内短路模型,设置内短路发展仿真计算时间为0.01 s,分析锂枝晶半径与电池电极固相体积分数等因素对电池电气特性与温度分布特性的影响。结果表明,初始内短路温度、短路电流、产热功率随时间的增加而增加,内短路温度和锂枝晶半径呈二次正相关关系,和体积分数呈线性关系,而和隔膜厚度、导热系数呈负相关关系;内短路发生后,去除电极处的温度限制,初始内短路温度随时间开始上升,锂枝晶半径为5μm、10μm时达到热失控起始温度的时间分别为4 s和1.8 s。本研究为锂离子电池运行过程中的温度检测及故障判断提供数据支撑,为新能源汽车隐患排查以及日常防范使用提供指导。

     

    Abstract: Internal short circuit of lithium dendrites is one of the main causes of thermal runaway in lithium-ion batteries for new energy vehicles. Understanding the characteristics of lithium-ion battery dendrites and temperature is beneficial for reducing the risk of internal short circuit thermal runaway in lithium batteries. In this paper, a model of electrochemical-thermal internal short circuit in lithium batteries is established, the simulation calculation time of internal short circuit development is 0.01 s, and the influence of factors such as the radius of lithium dendrites and the solid phase volume fraction of battery electrodes on the electrical and temperature distribution characteristics of the battery has been analyzed. The results show that the initial temperature of the internal short circuit, short-circuit current, and heat generation power increase with time. The internal short circuit temperature and lithium dendrite radius show a quadratic positive correlation, a linear relationship with volume fraction, and a negative correlation with membrane thickness and thermal conductivity. After the internal short circuit occurs, with the removal of temperature restrictions at the electrode, the initial temperature of the internal short circuit begins to rise over time. The time to reach the starting temperature of thermal runaway for lithium dendrite radii of 5 μm and 10 μm is 4 s and 1.8 s, respectively. This study provides data support for temperature detection and fault diagnosis during the operation of lithium-ion batteries, and guidance for hazard investigation and daily prevention in the use of new energy vehicles.

     

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